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Reduction Behavior of Sinter Based on Top Gas Recycling-Oxygen Blast Furnace

LAN Rong-zong , WANG Jing-song , HAN Yi-hua , SHE Xue-feng , WANG Lin-tao , XUE Qing-guo

钢铁研究学报(英文版)

In order to explore the behavior laws of sinter reduction in TGR-OBF (top gas recycling-oxygen blast furnace), reduction experiments of sinter have been conducted by thermal balance mass loss method with different atmospheres, temperatures and volume flows. The changes of RI (reduction degree of Fe2O3), RI′ (reduction rate of Fe2O3) and r (reduction degree of FeO) have been examined. The results show that the reduction of sinter was significantly improved under TGR-OBF atmosphere, and the RI and r were measured up to 98.2% and 97.8% at 900 ℃ respectively. With increasing of the reduction temperature, the reduction of sinter speeded up greatly, and the reduction time-duration shortened from 117 min at 900 ℃ to 63 min at 1100 ℃. Moreover, the reduction of sinter enhanced with increasing of the reductive gas flow. When the flow increased from 10 to 15 L/min, the initial reduction rate of sinter increased from 2.47%/min to 3.73%/min. While increasing H2 and CO contents in the reductive atmosphere, the reduction of sinter was promoted. Besides, H2 influenced more evidently than CO to the reduction of sinter, especially in the later stage of the reduction process, for instance, the reduction of wustite will be improved enormously when increasing the H2 content in the reductive atmosphere.

关键词: oxygen blast furnace , sinter , reduction

Comprehensive Utilization of Paigeite Ore Using Iron Nugget Making Process

DING Yin-gui , WANG Jing-song , WANG Guang , MA Sai , XUE Qing-guo

钢铁研究学报(英文版)

The feasibility of paigeite ore treatment with iron nugget making process is proved. The isothermal reduction experiments at laboratory scale were carried out, using carbon bearing pellets which were made of boron containing iron concentrate and pulverized coal mainly, from 1623 to 1723 K with different heating time. The results indicated that iron nugget making process depends mainly on heating time and temperature. And the iron nugget and slag can separate in a clean manner at 1673 K for 15 min. For the iron nugget, the C content is 357% (mass percent) and B is 0065% (mass percent). The B2O3 content of slag is 2001%, and the boron was concentrated into one phase which is identified as suanite (Mg2B3O5) during the solidification. With an extraction ratio of 80% under the atmospheric conditions, the activity of boron in slag is good. The boron-rich slag can be used to extract boric or boric acid and alleviate the shortage of boron resource. Through series of calculation and analysis related, it can be concluded that the recovery ratio of Fe and boron are about 98% and 97% respectively. The results show that this method is feasible and effective on the utilization of paigeite ore.

关键词: boron containing iron concentrate , carbon bearing pellets , iron nugget , boron-rich slag

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